Please use this identifier to cite or link to this item: http://er.chdtu.edu.ua/handle/ChSTU/376
Title: SPIN-ORBIT COUPLING EFFECTS IN BRO- AND HOBr PHOTODISSOCIATION REACTIONS
Authors: Хоменко, Олена Михайлівна
Keywords: photodissociation;absorption bands
Issue Date: 2014
Publisher: CHEMISTRY & CHEMICAL TECHNOLOGY
Abstract: Potential energy curves of the ground and a few excited states of the BrO- and HOBr along the photodissociation reactions, which correlate with lower dissociation limits are obtained on the base of calculations results by ab initio method. The singlet-triplet nonadiabatic transition with dissociation of the ground Х1S+ state to lower limit О(3Р) + Br-(1S) is predicted on the basis of calculations results. The ground singlet Х1S+ state of the BrO- has predissociative and metastable character for the upper vibrational levels. It is shown that the singlet-triplet transition to the lower triplet state a3A²¬X1A¢ is responsible for a weak HOBr absorption in the visible region (440–650 nm).
URI: http://er.chdtu.edu.ua/handle/ChSTU/376
Volume: 8
Issue: 2
First Page: 117
End Page: 121
Appears in Collections:Наукові публікації викладачів (БФ)

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